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Twelve gold spinor modes on four qubits

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Part 4 · compact hardware gate

Twelve fermionic spinor modes would normally require twelve qubits. With eleven electrons, however, there is exactly one hole. The physical space therefore contains only twelve basis states and fits exactly into four qubits.

The exact reduction

The dimension is C(12,11)=12. Four qubits provide sixteen computational basis states; twelve encode the one-hole states and four are padding. For the frozen, non-interacting Γ-point Hamiltonian, this compression removes no state from the chosen sector.

Because the initial state is known, we prepare it directly and perform real-time evolution. There is no parameterised ansatz and no optimiser—therefore no VQE landscape, barren plateau or repeated energy-minimisation loop.

IBM Kingston

Job d9r0lopdsedc73ag0f1g ran with 4096 shots on ibm_kingston. The raw result had a Hellinger fidelity of 0.762867 and a total-variation distance of 0.271808 relative to the exact distribution. Exact postselection onto the twelve valid codes raised the fidelity to 0.849566. M3 readout correction combined with the same postselection reached 0.858053.

Analysis route Hellinger fidelity TV distance
Raw 0.762867 0.271808
Raw + exact sector postselection 0.849566 0.197817
M3 + exact sector postselection 0.858053 0.188384

What mitigation means here

Postselection uses an exact symmetry: four of the sixteen strings cannot belong to the compact one-hole space. M3 corrects readout errors. Additional runs with dynamical decoupling and gate twirling are useful diagnostics, but a single time-ordered sequence on a drifting backend is not a clean causal experiment.

Claim boundary. This is a genuine material-derived QPU smoke test of compact one-particle dynamics. It contains no screened electron interaction, no full k-point integration and no prediction of gold’s colour. It is also not quantum advantage: a 12-dimensional sector is classically easy.
Project page: Relativistic gold

  1. Part 1: Why gold is a relativistic quantum problem
  2. Part 2: Why the 2025 gold VQE study stalled
  3. Part 3: From QE and spin–orbit coupling to Qiskit
  4. Part 4: Twelve gold spinor modes on four qubits
  5. Part 5: The 24-qubit route: an active window for transport
  6. Part 6: 24 qubits on IBM and with Fire Opal
  7. Part 7: The road to quantum advantage for gold

Sources and reproducibility

  • Quantum ESPRESSO methodology
  • Wannier90 methodology
  • IBM Qiskit: PauliEvolutionGate

Project status: 8 August 2026. Numerical values come from the frozen local research artifacts; the original claim boundaries are deliberately preserved.

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